PSG meet Barca in the first-leg of their quarterfinal tie next week.
Enrique said: "The games in the Champions are prepared well in advance.
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"I'm going to take it very calmly. I want to see my team play a very characteristic football. I want us to be competitive and have a great match.
"Our followers feel that we have a good team. It is a united team, which works hard and plays soccer well. It is a team that presses and gives joys.
"We are going to win the game, pass the round and be ambitious. We want to be humble and ambitious. I think a very special game awaits us in the Parc des Princes. We are going to try to be better than our adversaries."