And in another plum tie, West Ham have drawn Bundesliga leaders Bayer Leverkusen.
Serie A rivals AC Milan and Roma have also been pitted together.
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Quarter-finals draw
AC Milan v Roma
Liverpool v Atalanta
Bayer Leverkusen v West Ham
Benfica v Marseille
Semi-finals draw
Benfica or Marseille v Liverpool or Atalanta
AC Milan or Roma v Bayer Leverkusen or West Ham