Valencia will face Mexico next month.
Los Che will meet El Tri in Puebla in a friendly on October 12.
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The LaLiga club stated: "Valencia CF will use their trip to the Central American country to get closer to fans on the other side of the Atlantic. Mexico is a territory that is part of the club's international expansion project.
"The fixture will take place in the international break following the LALIGA EA Sports Matchday 9 match against CD Leganés."
