Deportiva Minera's shock Copa del Rey victory over Alaves last week has been rewarded with a dream tie against Real Madrid.
In this mornings draw, another giantkiller - Barbastro - will host Barcelona.
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Atletico Madrid, meawhile, will go to Marbella in this round of 32.
Copa del Rey round of 32 draw:
Barbastro-Barcelona
Pontevedra-Mallorca
Mining-Real Madrid Sports
Logroñés-Athletic
Marbella-Atlético de Madrid
Ponferradina-Real Society
Granada-Getafe
Huesca-Betis
Racing de Santander-Celta
Racing de Ferrol-Rayo Vallecano
Almería-Seville