Title holders Real Madrid will meet city rivals Atletico Madrid in the Champions League round of 16.
In today's draw, Liverpool were pitted against PSG and Arsenal with PSV Eindhoven. Fellow Premier League outfit Aston Villa will face Club Brugge.
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There is also an all-Bundesliga tie between Bayern Munich and Bayer Leverkusen.
The two-legged last 16 ties will be played on 4-5 March and 11-12 March.
Champions League round of 16 draw:
Paris St-Germain v Liverpool
Club Brugge v Aston Villa
PSV Eindhoven v Arsenal